This is a list of Kitui County Government ministers (CECs) as of 2021. Kitui County is headed by Governor Charity Ngilu.
Kitui county government structure consists of 8 County Executive Committee members as listed below.
Kitui County Government Ministers (CECs) 2021
| Ministry | Minister (CEC) | |
| 1 | Education, ICT and Youth Development | Stephen Kyalo Maithya |
| 2 | Trade, Cooperatives and Investments | Esther Kilonzi |
| 3 | Health and Sanitation | Winnie Syombua Kitetu |
| 4 | Gender, Sports and Culture | Hellen Kisiku Kitheka |
| 5 | Land and Physical Planning | Samson Nyamai Masila |
| 6 | Agriculture, Water and Livestock | Meshack Kyalo Muthusi |
| 7 | Livestock, Apiculture and Fisheries Development |
Emmanuel Malii Kisangau |
| 8 | Environment, Tourism and Natural Resources |
Patrick Koki Musau |
| 9 | Infrastructure, Housing, Transport and Public Works |
Jacob Maundu Kakundi |
